- Christopher Columbus as Ash Ketchum
- Gabriel Sanchez as Pikachu
- Queen Isabella I as Misty
- Ferdinand Columbus as Drew
- Beatriz Enriquez de Arana as May
- Antonion de Marchena as Max
- Adrian de Moxica as Cilan
- Martin Alonso Pinzon as Buizel
- Captain Mendez as Professor Birch
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