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- Caillou as Ash
- Sarah as Misty
- Andre as Brock
- Gilbert as Pikachu
- Linus (from Peanuts) as James
- Lucy (from Peanuts) as Jessie
- Diesel (from Thomas and Friends) as Meowth
- Clementine as May
- Leo as Max
- Rosie as Dawn
- Boris as Professor Oak
- Doris as Delia Ketchum