- Captain America/Steve Rogers as Fireman Sam
- Iron Man/Tony Stark as Elvis Criddlington
- Black Widow/Natasha Romanoff as Firefighter Penny Morris
- Winter Soldier/Bucky Barnes as Norman Price
- Baron Helmut Zemo as Bentley The Robot
- Agent 13/Sharon Carter as Bella Lasagne
- Thunderbolt Ross as Station Officer Steele
- Vision as Trevor Evans
- Scarlet Witch/Wanda Maximoff as Dilys Price
- Spider-Man/Peter Parker as James
- Christine Everhart as Sarah
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