- Captain America/Steve Rogers as Don Haskins
- Iron Man/Tony Stark as Adolph Rupp
- Black Widow/Natasha Romanoff as Mary Haskins
- Hawkeye/Clint Barton as Moe Iba
- The Falcon/Sam Wilson as Jerry Armstrong
- Black Panther/T'Challa as Willie Worsley/Willie 'Scoops' Cager
- Thunderbolt Ross as Orsten Artis
- Vision as Harry Flournoy
- Scarlet Witch/Wanda Maximoff as Mrs. Flournoy
- Spider-Man/Peter Parker as Bobby Joe Hill
- Christine Everhart as Tina Malichi
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