- Captain America/Steve Rogers as Bilbo
- Iron Man/Tony Stark as Smaug
- Crossbones/Brock Rumlow as Gandalf
- Winter Soldier/Bucky Barnes as Necromancer
- Black Panther/T'Challa as Thrandil
- Baron Helmut Zemo as Legolas
- Ant-Man/Scott Lang as Fili
- James Rhodes/War Machine as Kili
- Vision as Thorin
- Spider-Man/Peter Parker as Bard
- Peggy Carter as Taurial
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