- Charlie Chan as Ash Ketchum
- Yvonne Roland as Misty
- Betty Adams as May
- Richard Masters as Brock
- Lee Chan as Pikachu
- Arthur Hughes as Cilan
- Mr. Cartwright as Professor Birch
- Charlie Chan, Jr. as Harley
- Mr. Hopkins as Tracey
- Honorable Charles Zaraka as Gary Oak
- Inspector Strasser as Buizel
- Dr. Burton as Max
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