- Lieutenant Commander Ron Hunter as Ash Ketchum
- Captain Frank Ramsey as Brock
- Lieutenant Roy Zimmer as Pikachu
- Command Master Chief Walter Cob as Buizel
- Lieutenant Peter Ince as Gary Oak
- Lieutenant Bobby Dougherty as Richie
- Lieutenant Darik Westerguard as Max
- Officer of the Deck Mahoney as Professor Birch
- Chief of the Watch Hunsicker as Harley
- Tactical Supervising Officer Billy Linkletter as Cilan
- Lieutenant Paul Hellerman as Raichu
- and more
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