• James Bond as Ash Ketchum
  • Giacinta Johnson as Zoey
  • Gustav Graves as James
  • Miranda Frost as Jessie
  • Zao as Pikachu
  • M as Brock
  • Colonel Moon as Todd
  • General Moon as Professor Birch
  • Q as Tracey
  • Charles Robinson as Buizel
  • Peaceful Fountains of Desire as Buneary
  • Raoul as Harley

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