- James Bond as Ash Ketchum
- Giacinta Johnson as Zoey
- Gustav Graves as James
- Miranda Frost as Jessie
- Zao as Pikachu
- M as Brock
- Colonel Moon as Todd
- General Moon as Professor Birch
- Q as Tracey
- Charles Robinson as Buizel
- Peaceful Fountains of Desire as Buneary
- Raoul as Harley
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