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List of Whitney's Greatest Adventures characters is a fan-fiction thing to make.
- Whitney is the main character of the series. She is a pink haired girl who always tries best to be a very special girl. She is also described to be a crybaby. She is voiced by Megan Hollingshead.
- Jasmine is Whitney's best friend and a girl from Olivine City. She is a very talented girl and she is always trying to help someone. She is voiced by Tara Jayne in Season 1-9 and later by Alyson Leigh Rosenfeld in Season 10-Present.
- Janina is Jasmine's little sister. She is a green haired girl who always tries to be a great dancer. She, like Whitney, is also described to be a crybaby. She is voiced by Kerry Williams.
- Tierra is Whitney's best friend and an archaeologist. She is a red haired girl that always tries to be cute. She also like wearing casual clothes with black tights under her miniskirt. She is voiced by Amy Birnbaum.
- Liza is Whitney's best friend. She is a dragon tamer that always tries to be her best. She has green hair just like Janina. She is voiced by Liza Ortiz.
- Clair is Whitney's best friend and a gym leader from Blackthorn City. She is a blue haired girl that always tries to be kind. She also likes wearing normal clothes as usual. She is voiced by Megan Hollingshead.
- Courage is Whitney's pet dog. He is a timid animal that when he sees scary things, he lets out a scream. He is voiced by Marty Grabstein.