- Butch as Alvin (Butch and Alvin are both mischievous)
- Buttercup as Brittany (Buttercup and Brittany are both tomboys)
- Brick as Simon (Brick and Simon are both bookworms)
- Blossom as Jeanette (Blossom and Jeanette are both smart)
- Boomer as Theodore (Boomer and Theodore are both cute)
- Bubbles as Eleanor (Bubbles and Eleanor are both blonde)
- Professor Utonium as Dave
- Mrs. Keane as Samantha
- HIM as Miles
- Sedusa as Ashley
- Mojo Jojo as Agent James Suggs
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