• Riddick as Ash Ketchum
  • Colonel R. "Boss" Johns as Professor Birch
  • Santana as Mewtwo
  • Dahl as Dawn
  • Diaz as Pikachu
  • Moss as Buizel
  • Lockspur as Todd
  • Vargas as Turtwig
  • Luna as Cilan
  • Falco as Tracey
  • Nunez as Psyduck
  • Rubio as Harley
  • Siberius Vakko as Richie
  • Lex Branman as Max
  • Santana's Prisoner as Jessie

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