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- Bart as Kuzco
- Homer as Pacha
- Marge as Chicha
- Lenny and Lisa as Tipo and Chaca
- Principal Skinner as Kronk
- Edna Krabappel as Yzma (Edna Krabappel and Yzma are both Bossy and Stubborn)
- David Spade - Bart
- John Goodman - Homer
- Wendie Malick - Marge
- James Lopez - Lenny
- Kellyann Kelso - Lisa
- Patrick Warburton - Principal Skinner
- Eartha Kitt - Edna Krabappel