- Natasha Rostova as Marge Simpson
- Count Pierre Bezukhov as Homer Simpson
- Prince Andrei Bolkonsky as Waylon Smithers, Jr.
- Anatole Kuragine as Bart Simpson
- Napoleon as Grandpa Abe Simpson
- General Kutuzov as Barney Gumble
- Helene as Lisa Simpson
- Dolokhov as Otto
- Prince Vasili Kuragine as Ralph Wiggum
- Count Rostov as Mr. Burns
- Lise as Edna Krabappel
- Countess Rostova as Selma Bouvier
- Mary Bolkonskaya as Patty Bouvier
- Prince Bolkonsky as Chief Clancy Wiggum
- Sonya Rostova as Bernice Hibbert
- Nicholas Rostov as Ned Flanders
- Platon Karataev as Dr. Julius Hibbert
- Denisov as Sideshow Mel
- Petya Rostov as Bumblebee Man
- Russian Officer as Jasper Beardly
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